Tea-time masonry

A reader writes:

Could you build a tabletop cathedral out of sugar cubes?

What I mean is, of course you could build one out of soapstone, or soap, or wax, or whatever, but all of those are so strong you can get away with pretty much anything. Snow is weak but so light you can build a shelter out of it with no particular concern for architecture (though I once had an unpleasant surprise when it got warm overnight - "wait, should I really be seeing stars? and what's this weight on my legs?"). But sugar cubes are both heavy and fairly crumbly.

So could you build a cathedral of reasonable size and have to deal with similar engineering difficulties to those medieval stone-cathedral builders did?

Anne

Never having tried it myself, and not even having any sugar cubes in the house, I reckon you could build something pretty impressive with them. I think they may indeed be quite good analogues for unreinforced historic masonry, at around a 1:100 scale. And yes, this could be quite instructive, like the classic spaghetti-bridge exercise that also forces the architect to work with a material that behaves in small scale not unlike real construction materials at full scale, neutralising the square-cube law that tends to make models unrealistically sturdy.

(Look at this enormous model, for instance. It's held together with glue, which may reinforce the cubes significantly, or may not.)

The compressive, and tensile, strength of materials is defined in pascals, one pascal being one newton of force applied over an area of one square metre. Because of this rather large area, even quite feeble materials achieve strength scores up in the kilopascals (kPa).

If your sugar cube is, for the sake of argument, one centimetre square, its share of a 1 Pa pressure over a square metre would be only one ten-thousandth of a newton, which is the kind of pressure a marshmallow could withstand without visible deformation. Crank the pressure up to 10,000 Pa (ten kilopascals, kPa) and the sugar cube will be supporting a whole Newton, equal to a weight of about 100 grams under normal Earth gravity. This seems a plausible sort of strength for a sugar cube to manage.

The compressive strength of modern bricks and concrete blocks is up in the single-digit megapascals (or considerably higher, if the bricks or blocks don't have the usual holes through them); some natural stones are much stronger (granite manages around 200 MPa), but natural stone is likely to contain cracks and fissures that make the safe load limit considerably lower.

If sugar cubes turn out to actually be feeble, it might not actually matter that much, because the full compressive strength of masonry is surprisingly unimportant a lot of the time. You could build the Empire State Building out of stone, or possibly even ordinary bricks, and be in no danger of crushing the bottom blocks with the weight of the rest. That building would be spectacularly unsafe - even with a big reinforced concrete foundation to prevent it from subsiding into the earth, tilting and then toppling, things like wind stress and very minor seismic events could destabilise a giant stone tower very easily. (There is a reason why the longest-lived colossal stone structures in the world are approximately the shape that collapsing stonework naturally creates.) But compressive strength, at least, would not be a problem.

The centuries-old cathedrals that survive are, generally speaking, well engineered, but this is because they're the ones that didn't fall down. A lot did. Pre-scientific architecture was a trial-and-error, evolutionary process, in which people built things that looked as if they'd stay up, and then hoped that if the roof did fall in, it wouldn't be on a full Easter congregation. Sometimes there's evidence of a forced design review in the middle of a building's construction; the Bent Pyramid probably looks the way it does because it became clear to the builders half way through that they were making something too tall and pointy to stay up.

Very few collapses had anything to do with masonry being crushed by its own weight, though, except when some genius decided to use masonry like wood and, say, try to bridge pillars with a slab of stone (the ancient Greeks did this sort of thing quite often, which is why the Parthenon is as ruined as it is. There's a fabulous stack of broken lintels hidden inside the Great Pyramid, too; one broke, they put another one on top, it broke, they put another one on, that one burned down, fell over, and then sank into the swamp...).

Another great way to accidentally put masonry in tension is to put a darn great dome on your building, which will push down and out all around its base. Masonry must then be tricked into keeping force paths safely within the stone by contrivances like, for instance, flying buttresses. If you must have a huge dome, you either need a lot of these tricks, or a circle of very stout iron chain hidden inside the dome's base.

Getting back to sugar cubes, they're not actually all that dense, since they're a porous sintered aggregate of sugar particles (which is essential; a solid cubic crystal of sugar would look pretty neat, but you'd be waiting a while for it to dissolve in your tea). The density of sucrose is only about 1.6 grams per cubic centimetre in the first place.

So if we ballpark the mass of each once-centimetre cube as one gram, and set the ceiling supportable weight as 100 grams, we can stack 100 cubes on top of each other before the one at the bottom is under unacceptable strain. I've no idea how close these numbers actually are to reality, though, and there are no doubt considerable variations between different brands of sugar cubes (some of which are rectangular cuboids, not cubes at all), how they've been packed and otherwise treated, the same sugar cubes under different conditions (humidity, mainly), and so on. I invite actual experimental evidence from readers below; stack things on sugar cubes until they're crushed, and tell us how much weight your cubes can stand!

(In the above blather about historical architecture, any seeming brilliance on my part was actually just relayed from the author of two of my favourite books in the whole world, J.E. Gordon. The relevant book here is "Structures, Or Why Things Don't Fall Down", but "The New Science of Strong Materials, or Why You Don't Fall through the Floor" is also essential reading for anybody who, on reading those titles, realises that they don't really know why these unfortunate events do happen so seldom in the modern world.)


Psycho Science is a regular feature here. Ask me your science questions, and I'll answer them. Probably.

And then commenters will, I hope, correct at least the most obvious flaws in my answer.

Sweet speed

A reader writes:

How does the "sugar rush" work?

My kids go crazy when they get candy and soda (which they usually don't, but I'm not so cruel a mom as to feed them carrot sticks on their birthday), and on the rare occasions when I drink non-diet soda I get about 15 minutes of energy followed by a miserable crash... but now my doctor tells me that the sugar rush doesn't actually exist at all, so it's all in my head. And my kids' heads, too, apparently.

The doctor's not very tactful, but he's always seemed pretty sharp to me. Is he right?

Judy

Yes, your doctor is right. There's no such thing as a sugar rush. Sugar is not a stimulant, whether it's glucose, sucrose, the High-Fructose Corn Syrup that continues to rain stickily down on the entire population of North America, or any of the other sweet-tasting whatever-oses.

If you eat something with simple sugars in it that all pass into the bloodstream quickly - glucose, which doesn't need any digestion, being the simplest of all - you can end up messing with your body's sugar metabolism. Presuming you're not diabetic, your pancreas will pump out a lot of insulin to cope with the sugar bomb and then, when all of that sugar is quite suddenly dealt with, your body may find itself with an insulin surplus and give you a low-impact version of diabetic hypoglycemia. Lots of non-diabetic people have symptoms like this; it's even possible to feel the shaky, mind-fogged symptoms of mild hypoglycemia when your blood sugar and insulin levels are perfectly normal.

(The most important difference between "real" diabetic hypoglycemia and this pseudo-hypoglycemia is that the second version isn't dangerous. Just have a lie down, and in due course your body will drift back into homeostasis and you'll feel better. If a diabetic tries treating hypoglycemia that way, they can end up very ill, or dead.)

A transient hypoglycemic state does feel like a post-stimulant "crash", so there's solid basic biology behind that half of the "sugar rush" experience. There just isn't any actual rush at the start, unless you were hungry enough to feel faint when you ate that block of chocolate or drank that Humongous Gulp of fizzy sugar-water. And in that case, you again didn't get an actual rush, just a rapid return to normal function, which under the circumstances you could easily interpret as a rush.

(I'm ignoring, for the purposes of this discussion, the case of caffeinated drinks. Those certainly can give you some sort of "rush", followed by a crash, but it's not because of the sugar.)

So why do so many people swear that their kids go hyperactive when full of ultra-high-glycemic-index party food?

Well, it's partly because small children at birthday parties have a tendency to go nuts no matter what you feed them. And it's partly a placebo effect.

It doesn't seem as if it should be a placebo, though. If a child's had it drummed into them that they're expected to go hyperactive when they eat lollies, it wouldn't be terribly surprising if they did. But without such an expectation, sugar should have no particular placebo effect on the child.

But the placebo effect we're talking about here isn't happening to the child. It's happening to the adults who're observing the child. I don't know if there's been much research into this, but it's plausible for a couple of reasons. One is this study, which found that mothers who believed their young sons were "sugar sensitive" were more likely to perceive hyperactivity in their child if they're told the boy had been fed sugar, and less likely if they believed the boy had had an artificial sweetener, even though all of the children in the study actually got the artificial sweetener.

The second reason is that an analogous situation exists in veterinary medicine.

There are all sorts of nutty woo-woo alternative-medicine treatments available for animals, even openly preposterous activities like chiropractic adjustments for horses, performed by human beings with their bare hands. To actually shift the vertebrae of a horse around you'd need the assistance of the Incredible Hulk, or at least a very large mallet. But there the horse-chiros are, prodding and pushing and pretending something's moving (see also, "craniosacral therapy"...), and it's not hard to find horse owners who're convinced their animal's much healthier after the pantomime is complete.

So this is the placebo effect at one remove. The owner of the horse, or the parent of the child, can swear up and down that they see a clear difference, when one does not in fact exist.

(There can also be a direct placebo effect in veterinary medicine; an animal can be expected to change its behaviour if a strange person comes and messes with it, whether or not anything of real medical value is taking place. Animals are renowned for perking up when you take them to the vet, the usual explanation given being that they're in a scary environment and trying to look as strong and healthy as possible to avoid being selected for lunch by some unseen predator. This is a bit of a Just-So Story, though, because there's no way to prove it right or wrong until someone finds a talking dog. But never mind that for now.)

There are good reasons not to feed your kids a lot of sugar. But there's no reason to suppose, and several reasons to not suppose, that sugar has anything to do with hyperactivity.


Psycho Science is a regular feature here. Ask me your science questions, and I'll answer them. Probably.

And then commenters will, I hope, correct at least the most obvious flaws in my answer.

For medicinal purposes only

A reader writes:

Hey, I get cheese sweats too!

While we're on the subject, when I drink alcohol, especially spirits, it makes me feel warm, starting in the stomach and moving out. How "real" is this effect? I presume it's not actually changing my core body temperature, because that'd make a shot of Jack Daniels a life-threatening event. What's actually going on?

Derrick

Alcohol indeed does not change your core temperature, but it genuinely can change the distribution of heat in your body. Ethanol is a vasodilator; it causes the smooth muscle around blood vessels to relax and let more blood through. If the ambient temperature is cool, your peripheral blood vessels will naturally be somewhat constricted, reducing blood flow to your extremities; when the vessels dilate, more warm blood flows through those outer vessels, the tissue there thus warms up, and you feel warmer. Because some parts of you genuinely are.

In extreme situations, this can be dangerous. The reason why the body constricts outer blood vessels when it's cold is specifically to avoid losing valuable heat via the extremities. Knock back some Scotch when you're hypothermic and it'll make you feel better (because of both the vasodilatory warming effect, and the psychoactive effects of the alcohol), but you'll also accelerate heat loss and actually make the situation worse.

(For this reason, although St. Bernards are used for alpine rescue, they've never had little barrels of brandy hanging around their necks. Oh, and the whole vasodilator thing also made the traditional use of alcohol as a snake-bite remedy actually a really bad idea.)

In non-life-threatening situations, like when you're cold but not dangerously so and come in to sit by the fire in the ski lodge, alcohol may help you warm up by increasing blood flow through the extremities that're now being warmed by the fire. More prosaically, an alcoholic nightcap can help with that vicious circle where you get into bed with cold feet and your feet stay cold, because cold feet don't have the blood flow to produce much heat for the bedclothes to retain.


Psycho Science is a regular feature here. Ask me your science questions, and I'll answer them. Probably.

And then commenters will, I hope, correct at least the most obvious flaws in my answer.

Once again, why not try caustic soda?

A reader writes:

One of the many things wasting space in my brain is that cocaine is commonly cut with baby laxative.

The only evidence I can remember for this is 1980s action movies, though, so I could be wrong.

Presuming they actually do that, or did that... why? Baby laxative? Could you guys not find any cornflour, or something?

Eldon

The idea of cutting a drug - or adulterating-for-profit any number of other products, for that matter - is to bulk it out to increase your income, without making it obvious that you're bulking it out to increase your income.

So you can get away with a little watering-down of booze, or considerably more if you're selling freezing flavourless lager to people who are already drunk. (Whenever it's this easy to run a scam, you can bet on centuries of merciless effort on the part of opposing lawmen. You don't mess with the weights and measures people if you know what's good for you.)

You, presuming you're a seller of illegal drugs, could also get away with mildly moistening marijuana to increase its weight.

But you couldn't get away with mixing all your whiskey half-and-half with water; even if you're the only saloon in a one-horse town, you'll soon be finding rattlesnakes in your bed. A similar trick done with marijuana and oregano is similarly inadvisable.

To the eye, the Expensive Serious White-Powder Drugs all look much the same. If you're shooting a movie and need "heroin" or "cocaine", then glucose powder or bicarbonate of soda or, as you say, flour, could do the job. But they wouldn't pass muster for a second if properly tested - just taste would give away more than very slight cutting of real heroin or cocaine with sugar or bicarb, and non-soluble substances like flour in a drug that's supposed to be cooked up into a liquid or free base may also make themselves obvious before you've gotten away to a safe distance with the customer's money.

What you, the go-getting narcotics entrepreneur who likes his knees unbroken, want instead of these mere visual substitutes is something that looks, feels, tastes, smells and behaves as much as possible like the real thing. Whatever someone does with the drug you're selling, your cutting substance should do too, at least up until the final "actually getting high" test.

Oh, and the cutting substance also needs to be as inexpensive as possible, and preferably also not poisonous.

So this is how we ended up with odd products being used to cut drugs. The famous "baby laxative" is mannitol, a pleasingly harmless substance which probably won't even give a user the runs. You need to swallow tens of grams for it to have that effect; "swallowing" via your nose will presumably work, but you'll need to be someone very big in the advertising industry, or David Bowie in the mid-Seventies, to achieve the necessary volume.

(Freebasing ought to avoid the problem altogether, but has other risks.)

Another weird-but-surprisingly-common drug adulterant is levamisole, a compound whose primary legitimate use is as worming pills for animals and humans. Levamisole looks just like pure cocaine, doesn't show up in quick-and-dirty adulterant-detecting tests, and may be a little bit toxic to heavy users, but is largely harmless. It's therefore an immensely popular cocaine-cutting agent.

There are also old-wives'-tale drug adulterants. They're putting heroin in the marijuana these days, you know! And in ecstasy, too!

No, they aren't.

Well, OK, maybe at some point someone did this. There ain't no intelligence test to be a drug dealer. But adding a very expensive drug to a less expensive drug and then selling the result as if it was all the less expensive drug is not a good business model. Marijuana dipped in PCP costs more. (Though Dave doesn't need to know.)

The heroin-in-ecstasy thing may have arisen because there is a common practice of cutting relatively expensive MDMA with a relatively inexpensive amphetamine-family drug; the two go together pretty well, since straight MDMA has stimulant effects too. Then, if someone who's used to MDMA pills full of speed gets some that have little or no speed, they'll feel much less stimulated and say there must be some opiates in these new pills.

There's one more kind of drug adulterant, which I think reached its fullest flower in the Prohibition period in the USA. Once the drug you're selling becomes illegal no matter how much care you take in making it, you see, you might as well put any old crap in it, if it meets the above criteria of not being obvious or killing your customers too quickly. In Prohibition, this explained all of the booze with methanol, and worse, in it.

It's quite easy to make moonshine that has very little methanol in it. Hell, if you start with sugar and bread yeast and keep your equipment clean, your brew will never have any methanol in it at all.

But methanol gets you drunk just as good as ethanol. And during Prohibition, the kick a given bathtub gin had was one of its most important selling points. And ethanol is an antidote to methanol poisoning; it's amazing how long serious alcoholics can survive, and not even go blind, drinking contaminated booze, as long as the good alcohol significantly outweighs the bad.

Result: Methanol-contaminated booze, often deliberately made that way by cutting it with industrial wood alcohol. It was all over the damn place, making money for gangsters and slowly poisoning large numbers of people who just wanted to get peacefully drunk.

And it got even worse. There are other substances which, superficially, get you drunk. A chemical called tricresyl phosphate is one of them. Back in the Twenties, some geniuses figured this out, observed that exposure to modest amounts of tricresyl phosphate did not seem to cause people to drop dead, and started adulterating a patent medicine called Jamaica ginger with it.

Patent medicines loaded up with alcohol were a popular way to sneak around Prohibition, and the poorer end of the market, once again, naturally gravitated toward whatever cost the least and hit the hardest. Thanks to tricresyl phosphate, Jamaica ginger or "Jake" looked like a value winner.

And tens of thousands of people were, to a greater or lesser extent, crippled.

Hooray for prohibition!


Psycho Science is a regular feature here. Ask me your science questions, and I'll answer them. Probably.

And then commenters will, I hope, correct at least the most obvious flaws in my answer.

Short-stopping

A reader writes:

When I release the trigger on my old AEG power drill (so old that it's from when a power tool was an INVESTMENT), the motor takes at least a second to spin down to stationary.

When I release the trigger on my Black and Decker cordless drill, though, the chuck stops spinning instantly.

Why the difference? Is there a mechanical brake in there? Is this some sort of regenerative braking to keep the battery charged for longer? Is there just a lot of friction in the drill because they don't make them like they used to?

Timothy

Old-style power drills have a simple design, in which the trigger connects mains power to the drill motor, releasing the trigger disconnects the power, and if you want more than one speed you can maybe move a clunky slider to change between two gear ratios and count yourself lucky because in my day laddie we used to have a bit and brace made frae whalebone wi' a sandstone chuck, et cetera.

Most modern corded power drills have a proportional speed-control system, where the further you pull the trigger, the faster the motor spins. When you release the trigger with the drill spinning, though, the motor will still take its time spinning down, unless of course there's a source of outside friction like a bit in the chuck that's still sticking through a piece of wood.

This spin-down behaviour is natural for almost all rotary electric motors. If you don't count certain odd birds like stepper motors, any spinning electric motor will, when you disconnect the power, coast down to a halt.

Except, as you say, cordless drills always stop at pretty much the exact moment you release the trigger, as long as you're not spinning some large object with the drill, like a hole-saw or sanding drum. And even then, they stop pretty quickly.

The reason for this is that cordless drills use simple, inexpensive brushed DC motors. (Actually, brushless motors are starting to show up in fancy cordless tools, but I'll shamelessly handwave that awkward fact for the purposes of the current conversation.)

Brush motors are really easy to stop dead: You just short out the input terminals.

If you've got a bare DC motor sitting around somewhere - I'll wait, while you dig up your box of old radio-controlled car parts or smash open that useless bloody $5 electric screwdriver that the batteries never even properly fit into - you can demonstrate this for yourself. Spin the motor's spindle by hand, and then short the terminals on the back of the motor with a paper clip or something and spin the spindle again. In the second situation, the faster the spindle spins, the greater the braking power on it.

The reason for this is "back EMF", a special case of the counter-electromotive force which, in brief, causes the currents induced in a piece of metal by a magnetic field to create another magnetic field opposing the first one. You can make an "eddy current brake" that employs this force to convert motive power directly into heat in the brake assembly, without any friction; this is useful in everything from heavy industrial applications to the delicate aluminium-paddle magnetic brake that sticks out of the side of a laboratory balance, whose purpose is to stop the darn scales from swinging back and forth around the correct reading until the research project runs out of funding.

In brushed DC motors, back-EMF braking works really well, which is why it is, for instance, the normal braking system for the abovementioned electric radio-controlled cars. A fast-stopping drill is a desirable thing to have, too, so releasing the trigger disconnects the power from the motor, and shorts the terminals to each other. There's no simple way to do the same thing in an AC motor, so you don't get this feature in corded drills.

Back-EMF braking won't instantly stop a motor if it's turning fast enough. I've got a Dremel Stylus, for instance, which is a brilliant little tool for all of those jobs for which my old mains-powered Dremel is a bit too powerful and clumsy, but for which a cheap AA-powered Dremel or similar suspiciously inexpensive rotary tool would be too feeble. I think the Stylus has a simple brush motor in there (as you change its speed, it sings the distinctive song of a brush motor vibrating because of audio-frequency pulse-width modulated speed adjustment), but its top speed, as with all rotary multi-tools, is much higher than the top speed of a cordless drill. So when you turn the Stylus off, it stops pretty darn quickly, and quite a bit quicker than the mains-powered Dremel, but it still takes about a second to run down.


Psycho Science is a regular feature here. Ask me your science questions, and I'll answer them. Probably.

And then commenters will, I hope, correct at least the most obvious flaws in my answer.

A grilled 4-hydroxyphenethylamine sandwich

A reader writes:

When I eat cheese, I sweat. I don't really feel hot, I just break out in a sweat.

Sweating when you eat a curry, that I understand. Or a big hot dinner; that could actually physically heat you up. But cheese? WTF?

Don

There's a compound in aged cheese, tyramine, that induces the release of epinephrine (a.k.a. adrenaline), and some related neurotransmitters. The result is a sort of mini-fight-or-flight reaction, including a faster heartbeat and, as you say, sweating.

Tyramine affects different people differently; many people don't notice the effect at all. I think the effect can vary from day to day and depending on how much cheese you've eaten. It does for me, anyway; sometimes vintage cheddar gives me a cheese-sweat, sometimes it doesn't.

Speaking of which, the type of cheese definitely matters. Un-aged cheeses, like cream cheese or cottage cheese or Kraft Reprocessed 580-Nanometer Partially Homologated Polymer Dairy Analogue, contain very little tyramine. As a general rule, the stronger-flavoured the cheese, the more tyramine there'll be.

It's the tyramine, by the way, that makes it a bad idea to consume vintage cheese if you're also taking a monoamine oxidase inhibitor drug. Old-style "irreversible" MAOIs plot to kill you in a few different ways, one of which is giving you a massive blood-pressure spike if, in cheerful defiance of the common sense of more than half of the world's population, you eat something which used to be milk, but has been left to sit for years on end and is now a stinking mould-covered lump of obviously lethal putrescence.


Psycho Science is a regular feature here. Ask me your science questions, and I'll answer them. Probably.

And then commenters will, I hope, correct at least the most obvious flaws in my answer.

Please at least pay us for the postage

A reader writes:

I don't know if this really qualifies as a science question, but: How do bills for zero dollars and zero cents get sent to people?

I'm guessing that it's something like the process you explained that leads to crazy negative numbers in installer disk-space calculations - maybe the system's screwed up and thinks you owe negative money (or you really do, because you overpaid), but there's a sanity check that rounds negative numbers to zero, and then fails to stop a bill being sent anyway.

Am I right?

Jiri

Exactly this sort of thing has been referred to since time immemorial, or at least since the early days of office automation...

...as a "computer error".

Which it isn't, of course. Once in a very long while a cosmic-ray strike or failing power supply or actual hardware defect does really cause a computer to make an error, but the overwhelming majority of "computer errors" are actually programmer errors. The computer is doing exactly what it was told to do, whether that's sending a bill for $0.00, or charging a startled pensioner for a hundred million kilowatt-hours of electricity, or falsely saying an e-mail came from FinkyPieheimer@zoobatz.com.

One programming error that can lead to a zero dollar bill - and, in due course, to second requests and final demands and then the attention of lawyers, if only because the lawyers are happy to round the ten seconds needed to recognise the mistake up to about ten billable hours - is using the wrong kind of variable.

In the real world, money comes in dollars and cents, pounds and pennies, rupees and extremely un-valuable paise, and so on. There's no such thing as a fraction-of-a-cent coin.

In computers, everything can be chopped up into arbitrarily small pieces, if necessary. There may be some good reason to do this for certain calculations applied to currency amounts (though I can't think of one), but if you do, before any of the results get turned into actual money being paid into accounts or demanded from clients, the numbers should be rounded into an integer number of cents (or whatever other currency unit's being dealt with).

(This process can be exploited, in the classic "salami slicing" scam where a great many fractions of a cent are sneakily diverted to the scammer's account by, for instance, always rounding down, even when the fraction being rounded is larger than 0.5.)

If a programmer uses, say, a single-precision floating-point variable to hold a monetary value, it's easy for the limited precision of the variable to, when mathematical operations are performed on it, end up at 0.9999 (probably with a few more digits) instead of 1, or 0.0001 instead of zero. In the latter case, a system that doesn't round off the imprecise value to what it should be, and subsequently starts the billing process on any account where the amount owing is greater than zero, will send idiotic zero-bills to customers.

(Or the only slightly less stupid version, a bill for an amount less than what the company paid to post the bill to you.)

There are many other ways for this to happen, though, thanks to the many ways in which programmers can make a mistake. A billing system could, for instance, fail to notice previous overpayment, decide to send a bill, then apply the overpayment to the account balance and send a bill for the net amount, which could be zero or negative. Or it could decide to send a bill to a customer who legitimately owes money, and then accidentally print the amount that some other, fully paid-up, customer owes on the bill.

Just because a company's got thousands of employees and annual turnover greater than the whole economy of some nations does not preclude this from happening. As Daily WTF readers know, staggeringly expensive "enterprise" software can be very, very badly written.


Psycho Science is a regular feature here. Ask me your science questions, and I'll answer them. Probably.

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There's nothing like a nice caustic soda facial scrub

A reader writes:

What's the chemical difference between soap and detergent? I know soap's made by reacting an oily substance and an alkali; is detergent made some other way?

Jun

Soap is, as you say, a class of substances with a clear chemical definition; a soap is a salt of a fatty acid. Soap molecules, in brief, are hydrophilic on one end and lipophilic on the other, and so allow oils to disperse in water.

Detergents are less clearly defined. One old definition of "detergent" says it's just any substance you use to clean something. By that definition, plain water is the most common detergent, and soap is detergent too. Sand counts as a detergent by this definition, because you can scour pots with it.

The standard home-and-garden definition of a detergent is, of course, much more limited; it covers dishwashing liquid, dishwasher powder, laundry liquid and powder, and so on. Any consumable cleaning substance that doesn't come in a solid bar, or in a pump-pack with "Soap" written on it somewhere.

These detergents contain one or more surfactants that do something similar to what soap does - often the ubiquitous sodium lauryl and/or laureth sulfate, which are not actually incredibly good at cleaning, but are very good at making the rich bubbly lather that consumers have been trained to equate with cleaning power. On top of that, there's "builders" that make the surfactant work better, and various other substances suited to the application. Oh, and in the case of liquid detergents, there's also quite a lot of water, which I've heard referred to by a formulator of shampoo and conditioner as "profitrol".

There are lots of substances that, like plain water, can fill the role of a detergent without containing surfactants. Sodium carbonate or bicarbonate, for instance, can be used as a fairly effective remover of oily substances all by themselves, essentially because they're alkaline and make a little of their own soap from whatever oils are on the thing to be cleaned. Sodium carbonate and bicarbonate are, however, not alkaline enough to be dangerous (unlike the standard soap-making alkali, sodium hydroxide), and also quite non-toxic, so you can use them straight as dishwasher powder with decent results if you're out of the detergent-y stuff.

(Note that some non-standard cleaning products actually have little or no effect at all. The classic example is the magical plastic laundry ball, which doesn't actually do anything, but may appear to work without any other detergent because plain detergent-less water will clean your clothes to some extent all by itself. See also, stone soup.)


Psycho Science is a regular feature here. Ask me your science questions, and I'll answer them. Probably.

And then commenters will, I hope, correct at least the most obvious flaws in my answer.